Alloy Overview

Grade 702 is a commercially pure zirconium grade with a minimum zirconium content of 99.2% (including a maximum of 4.5% hafnium). It contains controlled levels of iron (Fe), chromium (Cr), and oxygen (O), retaining zirconium’s inherent corrosion resistance while offering balanced mechanical properties. This grade is valued for its formability and reliability in aggressive environments.

Chemical Composition (Weight %)

ComponentContent Range
Zr (Zr + Hf)Min 99.2 (balance)
Fe + Cr0.2
HfMax 4.5
O0.16

Physical Properties

PropertyMetricEnglish
Density6.5 g/cc0.235 lb/in³

Mechanical Properties

PropertyMetricEnglishNotes
Hardness (Rockwell A)4949Estimated from Vickers
Hardness (Rockwell B)7878Estimated from Vickers
Hardness (Vickers)150150Annealed sample
Tensile Strength (Ultimate)Min 379 MPaMin 55,000 psi 
Tensile Strength (Yield, 0.2%)Min 207 MPaMin 30,000 psi0.2% offset
Elongation at Break16%16%Measured in 50 mm
Modulus of Elasticity99.3 GPa14,400 ksi 
Poisson’s Ratio0.350.35 
Shear Modulus36.2 GPa5,250 ksi 
Fatigue Strength (Notched)125 MPa18,100 psi5×10⁵ cycles
Fatigue Strength (Unnotched)145 MPa21,000 psi3×10⁷ cycles
Fatigue Strength (Unnotched)175 MPa25,400 psi5×10³ cycles
Fatigue Strength (Notched)60 MPa8,700 psi3×10⁷ cycles

Electrical & Magnetic Properties

PropertyMetricEnglishNotes
Electrical Resistivity3.97e-005 ohm-cm3.97e-005 ohm-cmTemp coefficient: 0.0044/°C at 20°C
Magnetic Susceptibility1.34e-006 cgs/g1.34e-006 cgs/gPure Zr
Critical Magnetic Field Strength47 oersted47 oerstedPure Zr
Critical Superconducting Temperature0.595 – 0.625 K0.595 – 0.625 KPure Zr

Thermal Properties

PropertyMetricEnglishNotes
Heat of Fusion250 J/g108 BTU/lb 
Linear CTE (20°C)5.89 μm/m-°C3.27 μin/in-°FMeasured at 25°C
Linear CTE (250°C)6.3 μm/m-°C3.5 μin/in-°F 
Linear CTE (500°C)6.9 μm/m-°C3.83 μin/in-°F 
Specific Heat Capacity0.285 J/g-°C0.0681 BTU/lb-°F 
Thermal Conductivity22 W/m-K153 BTU-in/hr-ft²-°F 
Melting Point1852°C3370°F 

Optical Properties

PropertyMetricEnglishNotes
Emissivity (0-1)0.320.32650 nm; unoxidized pure Zr sample; total

Key Features & Applications

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